{"id":939,"date":"2025-02-10T09:32:48","date_gmt":"2025-02-10T09:32:48","guid":{"rendered":"https:\/\/expanite.com?page_id=939"},"modified":"2026-08-13T07:27:29","modified_gmt":"2026-08-13T07:27:29","slug":"sigma","status":"publish","type":"page","link":"https:\/\/expanite.com\/it\/indurimento-superficiale\/whitepaper\/fase-sigma-duplex\/","title":{"rendered":"Fase sigma nei duplex"},"content":{"rendered":"<p><img decoding=\"async\" src=\"\/wp-content\/uploads\/2025\/01\/arrow-down.svg\" alt=\"\"><\/p>\n<h1>Sigma Phase(\u03c3)<\/p>\n<p><span class=\"uk-text-warning\">in Duplex<\/span><\/p>\n<\/h1>\n<h2>Preventing \u03c3-Phase Precipitation with Expanite\u00ae Treatments. <\/h2>\n<div>\n<p>Duplex stainless steels contain 2 types of microstructures, <a href=\"https:\/\/en.wikipedia.org\/wiki\/Austenite\" target=\"_blank\" rel=\"noopener\">austenite<\/a> and <a href=\"https:\/\/en.wikipedia.org\/wiki\/Ferrite_(magnet)\" target=\"_blank\" rel=\"noopener\">ferrite<\/a>. Hence the name duplex.<\/p>\n<\/div>\n<div>In simple terms, the combination of these two phases is what causes duplex alloys to be highly sensitive with respect to the formation of the so-called \u201cSigma phase\u201d (\u03c3-phase), because the \u03c3-phase primarily will form in the boundary between austenite and ferrite, growing into the ferrite.<\/p>\n<p><p>Sigma phase leaves the material in a stage with unfortunate material properties and must be prevented. Sigma phase forms primarily at 800-850C, but is able to form at temperature between 600 and 1000C, and will do so at varying rates, depending on the specific alloy. Please refer to the below TTT (Time-Temperature-Transformation) diagram for SAF2205 and the speed of which foreign phases forms.<\/p>\n<p>For example, then chromium nitrides, chi-phase and carbides forms if a part made from SAF2205 is held at 800C for more than 1 min. The critical \u03c3-phase precipitation will form after approximately 16 min.During our tests, Zeron100 SuperDuplex alloy proved worst results as it initiated formation of \u03c3-phase after 3.5 min. at 850C.<\/p>\n<\/div>\n<p><img decoding=\"async\" src=\"\/wp-content\/uploads\/2025\/02\/Sigmaphase.png\" alt=\"Preventing \u03c3-Phase\"><\/p>\n<hr>\n<p><p>\n        <a href=\"\/wp-content\/uploads\/2025\/02\/Sigma-Phase-in-Duplex-.pdf\">Download White Paper<\/a>\n    <\/p>\n<\/p>\n<p><img decoding=\"async\" src=\"\/wp-content\/uploads\/2025\/05\/CL_3-1.jpg\" alt=\"Sigma phase and Surface Hardening Expert\"><\/p>\n<h2>Need assistance?<\/h2>\n<div>Our team is available across all time zones to assist you with any inquiries.<br \/>\nShare your challenges with us, and we\u2019ll work together to find the perfect solution.<\/div>\n<ul>\n<li>\n<p>\n        <a href=\"https:\/\/expanite.com\/surface-hardening-heat-treatment-contact-experts\/\">Find Expanite Near You <\/a>\n    <\/p>\n<\/li>\n<li>\n<p>\n        <a href=\"tel:004528196443\">+45 2819 6443<\/a>\n    <\/p>\n<\/li>\n<\/ul>\n<p><p>\n        <a href=\"https:\/\/forms.zohopublic.com\/thomasabelsandholdt\/form\/Letushelp\/formperma\/HSzRaqV0nghd7JGxHm53zxMQyrI3eMWFfn_Q_tYMYJg\" target=\"_blank\" rel=\"noopener\">Contact Us<\/a>\n    <\/p>\n<\/p>\n<p><!--more--><br \/>\n<!-- {\"type\":\"layout\",\"children\":[{\"type\":\"section\",\"props\":{\"height\":\"viewport\",\"height_viewport\":60,\"height_viewport_offset\":true,\"image_loading\":true,\"image_position\":\"center-center\",\"image_size\":\"cover\",\"image_width\":\"2560\",\"media_overlay\":\"rgba(0, 30, 53, 0.39)\",\"padding_bottom\":\"large\",\"padding_top\":\"large\",\"style\":\"secondary\",\"text_color\":\"light\",\"title_breakpoint\":\"xl\",\"title_position\":\"top-left\",\"title_rotation\":\"left\",\"vertical_align\":\"bottom\",\"width\":\"default\"},\"children\":[{\"type\":\"row\",\"children\":[{\"type\":\"column\",\"props\":{\"image_position\":\"center-center\",\"position_sticky_breakpoint\":\"m\"},\"children\":[{\"type\":\"image\",\"props\":{\"image\":\"wp-content\/uploads\/2025\/01\/arrow-down.svg\",\"image_svg_color\":\"emphasis\",\"image_width\":45,\"margin_bottom\":\"default\",\"margin_top\":\"default\"}},{\"type\":\"headline\",\"props\":{\"content\":\"Sigma Phase(\u03c3)\\n\n\n<p><span class=\\\"uk-text-warning\\\">in Duplex<\/span><\/p>\n\n\",\"content_de_de\":\"Sigma Phase(\u03c3)\\n\n\n<p><span class=\\\"uk-text-warning\\\">in Duplex Edelstahlen<\/span><\/p>\n\n\",\"content_it_it\":\"Fase Sigma(\u03c3)\\n\n\n<p><span class=\\\"uk-text-warning\\\">in Duplex<\/span><\/p>\n\n\",\"image_align\":\"left\",\"image_margin\":\"xsmall\",\"margin_bottom\":\"small\",\"margin_top\":\"small\",\"maxwidth\":\"2xlarge\",\"maxwidth_breakpoint\":\"m\",\"title_color\":\"success\",\"title_element\":\"h1\",\"title_style\":\"heading-small\"}}]}]}],\"name\":\"Hero\"},{\"type\":\"section\",\"props\":{\"image_position\":\"center-center\",\"padding_bottom\":\"xsmall\",\"padding_top\":\"xsmall\",\"style\":\"primary\",\"title_breakpoint\":\"xl\",\"title_position\":\"top-left\",\"title_rotation\":\"left\",\"vertical_align\":\"middle\",\"width\":\"default\"},\"children\":[{\"type\":\"row\",\"children\":[{\"type\":\"column\",\"props\":{\"image_position\":\"center-center\",\"position_sticky_breakpoint\":\"m\"},\"children\":[{\"type\":\"breadcrumbs\",\"props\":{\"show_current\":true,\"show_home\":true}}]}]}]},{\"type\":\"section\",\"props\":{\"image_position\":\"center-center\",\"padding_bottom\":\"none\",\"style\":\"default\",\"title_breakpoint\":\"xl\",\"title_position\":\"top-left\",\"title_rotation\":\"left\",\"vertical_align\":\"\",\"width\":\"default\"},\"children\":[{\"type\":\"row\",\"props\":{\"column_gap\":\"large\",\"layout\":\"2-3,1-3\",\"margin_bottom\":\"medium\",\"margin_top\":\"medium\",\"row_gap\":\"large\"},\"children\":[{\"type\":\"column\",\"props\":{\"image_position\":\"center-center\",\"position_sticky_breakpoint\":\"m\",\"width_medium\":\"2-3\"},\"children\":[{\"type\":\"headline\",\"props\":{\"content\":\"Preventing \u03c3-Phase Precipitation with Expanite\u00ae Treatments. \",\"content_de_de\":\"Verhinderung von \u03c3-Phasen-Ausf\u00e4llungen mit Expanite\u00ae Behandlungen\",\"content_it_it\":\"Fase sigma negli acciai duplex? Non con l'espanite!\",\"image_align\":\"left\",\"image_margin\":\"xsmall\",\"title_element\":\"h2\",\"title_style\":\"heading-small\"}},{\"type\":\"text\",\"props\":{\"column_breakpoint\":\"m\",\"content\":\"\n\n<p>Duplex stainless steels contain 2 types of microstructures, <a href=\\\"https:\/\/en.wikipedia.org\/wiki\/Austenite\\\">austenite<\/a> and <a href=\\\"https:\/\/en.wikipedia.org\/wiki\/Ferrite_(magnet)\\\">ferrite<\/a>. Hence the name duplex.<\/p>\n\n\",\"content_de_de\":\"Duplex-Edelst\u00e4hle enthalten zwei Arten von Mikrostrukturen, Austenit und Ferrit. Daher der Name duplex.\",\"content_it_it\":\"Quando si forma la fase \u03c3?\",\"margin_bottom\":\"default\",\"margin_top\":\"default\",\"text_style\":\"lead\"}},{\"type\":\"text\",\"props\":{\"column_breakpoint\":\"m\",\"content\":\"In simple terms, the combination of these two phases is what causes duplex alloys to be highly sensitive with respect to the formation of the so-called \u201cSigma phase\u201d (\u03c3-phase), because the \u03c3-phase primarily will form in the boundary between austenite and ferrite, growing into the ferrite.\n\n<p>\\n\n\n<p>Sigma phase leaves the material in a stage with unfortunate material properties and must be prevented. Sigma phase forms primarily at 800-850C, but is able to form at temperature between 600 and 1000C, and will do so at varying rates, depending on the specific alloy. Please refer to the below TTT (Time-Temperature-Transformation) diagram for SAF2205 and the speed of which foreign phases forms.<\/p>\n\n\\n\n\n<p>For example, then chromium nitrides, chi-phase and carbides forms if a part made from SAF2205 is held at 800C for more than 1 min. The critical \u03c3-phase precipitation will form after approximately 16 min.During our tests, Zeron100 SuperDuplex alloy proved worst results as it initiated formation of \u03c3-phase after 3.5 min. at 850C.<\/p>\n\n\",\"content_de_de\":\"In einfachen Worten ist die Kombination dieser beiden Phasen der Grund daf\u00fcr, dass Duplex-Legierungen sehr empfindlich in Bezug auf die Bildung der sogenannten \\\"Sigma-Phase\\\" (\u03c3-Phase) sind, da die \u03c3-Phase haupts\u00e4chlich an der Grenze zwischen Austenit und Ferrit entsteht und in den Ferrit hineinw\u00e4chst.\\n\n\n<p> \n\n<p>\\n    Die Sigma-Phase hinterl\u00e4sst das Material in einem Zustand mit ungew\u00fcnschten Materialeigenschaften und sollte verhindert werden. Die Sigma-Phase bildet sich haupts\u00e4chlich bei 800-850\u00b0C, kann aber auch bei Temperaturen zwischen 600 und 1000\u00b0C entstehen und tut dies in unterschiedlichem Ma\u00dfe, abh\u00e4ngig von der spezifischen Legierung.\\n\n\n<p> \n\n<p>\\nBitte beachten Sie das folgende ZTU-Diagramm (Zeit-Temperatur-Umwandlung) f\u00fcr SAF2205 und die Geschwindigkeit, mit der Fremdphasen entstehen. Zum Beispiel bilden sich Chromnitride, Chi-Phasen und Karbide, wenn ein Teil aus SAF2205 l\u00e4nger als 1 Minute bei 800\u00b0C gehalten wird. Die kritische \u03c3-Phasen-Ausscheidung erfolgt nach etwa 16 Minuten.\\n\n\n<p> \n\n<p>\\nW\u00e4hrend unserer Tests zeigte die Zeron100 SuperDuplex-Legierung die schlechtesten Ergebnisse, da sie nach 3,5 Minuten bei 850\u00b0C die Bildung der \u03c3-Phase einleitete.\",\"content_it_it\":\"Gli acciai inossidabili duplex contengono due tipi di microstruttura, austenite e ferrite. Da qui il nome duplex. In parole povere, la combinazione di queste due fasi \u00e8 il motivo per cui le leghe duplex sono molto sensibili alla formazione della cosiddetta \u201cfase sigma\u201d (fase \u03c3), poich\u00e9 la fase \u03c3 si forma principalmente al confine tra austenite e ferrite e cresce nella ferrite..\\n\n\n<p> \n\n<p>\\nLa fase sigma lascia il materiale in uno stato con propriet\u00e0 indesiderate e deve essere evitata. La fase sigma si forma principalmente a 800-850\u00b0C, ma pu\u00f2 formarsi anche a temperature comprese tra 600 e 1000\u00b0C e lo fa in misura variabile, a seconda della lega specifica.\\n\n\n<p> \n\n<p>\\nSi noti il seguente diagramma TTT (trasformazione tempo-temperatura) per SAF2205 e la velocit\u00e0 di formazione delle fasi estranee. Ad esempio, nitruri di cromo, fasi chi e carburi si formano quando una parte di SAF2205 viene tenuta a 800\u00b0C per pi\u00f9 di 1 minuto. La precipitazione critica della fase \u03c3 si verifica dopo circa 16 minuti.\\n\n\n<p> \n\n<p>\\nDurante i nostri test, la lega Zeron100 SuperDuplex ha mostrato i risultati peggiori, in quanto ha iniziato la formazione della fase \u03c3 dopo 3,5 minuti a 850\u00b0C.\",\"margin_bottom\":\"default\",\"margin_top\":\"default\"}},{\"type\":\"image\",\"props\":{\"image\":\"wp-content\/uploads\/2025\/02\/Sigmaphase.png\",\"image_alt\":\"Preventing \u03c3-Phase\",\"image_svg_color\":\"emphasis\",\"margin_bottom\":\"default\",\"margin_top\":\"default\"}},{\"type\":\"divider\",\"props\":{\"divider_element\":\"hr\",\"divider_style\":\"icon\",\"margin_bottom\":\"large\",\"margin_top\":\"large\"}},{\"type\":\"button\",\"props\":{\"fullwidth\":false,\"grid_column_gap\":\"small\",\"grid_row_gap\":\"small\",\"margin_bottom\":\"default\",\"margin_top\":\"default\"},\"children\":[{\"type\":\"button_item\",\"props\":{\"button_style\":\"primary\",\"content\":\"Download White Paper\",\"dialog_layout\":\"modal\",\"dialog_offcanvas_flip\":true,\"icon_align\":\"left\",\"link\":\"wp-content\/uploads\/2025\/02\/Sigma-Phase-in-Duplex-.pdf\",\"link_de_de\":\"wp-content\/uploads\/2025\/05\/Sigma_Phase_Duplex_Expanite_Ger.pdf\",\"link_it_it\":\"wp-content\/uploads\/2025\/05\/Whitepaper_Sigma_Phase_Duplex_Expanite_IT.pdf\"}}],\"name\":\"need help buttons\"}]},{\"type\":\"column\",\"props\":{\"image_position\":\"center-center\",\"position_sticky\":\"column\",\"position_sticky_breakpoint\":\"m\",\"position_sticky_offset\":\"90\",\"width_medium\":\"1-3\"},\"children\":[{\"type\":\"module_position\",\"props\":{\"breakpoint\":\"m\",\"content\":\"sidebar\",\"layout\":\"stack\"}},{\"type\":\"image\",\"props\":{\"image\":\"wp-content\/uploads\/2025\/05\/CL_3-1.jpg\",\"image_alt\":\"Sigma phase and Surface Hardening Expert\",\"image_svg_color\":\"emphasis\",\"margin_bottom\":\"default\",\"margin_top\":\"default\"}},{\"type\":\"headline\",\"props\":{\"content\":\"Need assistance?\",\"content_de_de\":\"Ben\u00f6tigen Sie Unterst\u00fctzung?\",\"content_fr_fr\":\"Besoin d\u2019aide ?\",\"content_it_it\":\"Hai bisogno di assistenza?\",\"image_align\":\"left\",\"image_margin\":\"xsmall\",\"title_element\":\"h2\"},\"name\":\"CTA Headline Languages\"},{\"type\":\"text\",\"props\":{\"column_breakpoint\":\"m\",\"content\":\"Our team is available across all time zones to assist you with any inquiries.\\nShare your challenges with us, and we\u2019ll work together to find the perfect solution.\",\"content_de_de\":\"\n\n<p>Unser Team steht Ihnen weltweit zur Verf\u00fcgung und hilft Ihnen gerne bei Ihren Anfragen. Teilen Sie uns Ihre Herausforderungen mit \u2013 gemeinsam finden wir die perfekte L\u00f6sung.<\/p>\n\n\",\"content_fr_fr\":\"\n\n<p>Notre \u00e9quipe est disponible dans tous les fuseaux horaires pour r\u00e9pondre \u00e0 vos questions. Partagez vos d\u00e9fis avec nous et trouvons ensemble la solution id\u00e9ale.<\/p>\n\n\",\"content_it_it\":\"\n\n<p>Il nostro team \u00e8 disponibile in tutti i fusi orari per supportarti con qualsiasi richiesta. Condividi con noi le tue sfide e troveremo insieme la soluzione perfetta.<\/p>\n\n\",\"margin_bottom\":\"default\",\"margin_top\":\"default\"},\"name\":\"CTA Text all 4 languages\"},{\"type\":\"button\",\"props\":{\"fullwidth\":true,\"grid_column_gap\":\"small\",\"grid_row_gap\":\"small\",\"margin_bottom\":\"default\",\"margin_top\":\"default\"},\"children\":[{\"type\":\"button_item\",\"props\":{\"button_style\":\"default\",\"content\":\"Find Expanite Near You \",\"content_de_de\":\"Expanite-Standort finden\",\"content_fr_fr\":\"Trouver Expanite pr\u00e8s de chez vous\",\"content_it_it\":\"Trova Expanite vicino a te\",\"dialog_layout\":\"modal\",\"dialog_offcanvas_flip\":true,\"icon_align\":\"left\",\"link\":\"https:\/\/expanite.com\/surface-hardening-heat-treatment-contact-experts\/\",\"link_de_de\":\"de\/kontakt-de\/\",\"link_fr_fr\":\"fr\/contact\/\",\"link_it_it\":\"it\/contact\/\"}},{\"type\":\"button_item\",\"props\":{\"button_style\":\"primary\",\"content\":\"+45 2819 6443\",\"dialog_layout\":\"modal\",\"dialog_offcanvas_flip\":true,\"icon_align\":\"left\",\"link\":\"tel:004528196443\"}}],\"name\":\"need help buttons Languages\"},{\"type\":\"button\",\"props\":{\"fullwidth\":true,\"grid_column_gap\":\"small\",\"grid_row_gap\":\"small\",\"margin_bottom\":\"default\",\"margin_top\":\"default\"},\"children\":[{\"type\":\"button_item\",\"props\":{\"button_style\":\"secondary\",\"content\":\"Contact Us\",\"content_de_de\":\"Kontaktieren Sie uns\",\"content_fr_fr\":\"Contactez-nous\",\"content_it_it\":\"Contattaci\",\"dialog_layout\":\"modal\",\"dialog_offcanvas_flip\":true,\"icon_align\":\"left\",\"image_height\":\"800\",\"image_width\":\"400\",\"lightbox\":true,\"link\":\"https:\/\/forms.zohopublic.com\/thomasabelsandholdt\/form\/Letushelp\/formperma\/HSzRaqV0nghd7JGxHm53zxMQyrI3eMWFfn_Q_tYMYJg\",\"link_de_de\":\"https:\/\/forms.zohopublic.com\/thomasabelsandholdt\/form\/Lassunshelfen\/formperma\/cMO8p29KYK2Ds0D5khbNqshsAtmdrNYbl9zXZiYgj10\",\"link_fr_fr\":\"https:\/\/forms.zohopublic.com\/thomasabelsandholdt\/form\/Allonsaider\/formperma\/0r9cahpdBiAGUMQ4dAoV6kKb4T9XdMHDQlUQffuASN4\",\"link_it_it\":\"https:\/\/forms.zohopublic.com\/thomasabelsandholdt\/form\/SitoweblasciaciaiutartiIT\/formperma\/ibPLcnD9kKa016-fQ9sZYwFg8gcGLMPJ4ZNjo13zfb0\"}}],\"name\":\"Zoho form contact button All Languages\"}]}]}],\"name\":\"Post\"},{\"type\":\"section\",\"props\":{\"image_position\":\"center-center\",\"style\":\"default\",\"title_breakpoint\":\"xl\",\"title_position\":\"top-left\",\"title_rotation\":\"left\",\"vertical_align\":\"middle\",\"width\":\"default\"},\"children\":[{\"type\":\"row\",\"children\":[{\"type\":\"column\",\"props\":{\"image_position\":\"center-center\",\"position_sticky_breakpoint\":\"m\"}}]}]}],\"version\":\"5.0.34\"} --><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Fase sigma nei duplex &#8211; Expanite Indurimento superficiale<\/p>\n","protected":false},"author":2,"featured_media":169,"parent":928,"menu_order":2,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":"","advanced-sidebar-menu\/link-title":"","advanced-sidebar-menu\/exclude-page":false},"class_list":["post-939","page","type-page","status-publish","has-post-thumbnail","hentry"],"_links":{"self":[{"href":"https:\/\/expanite.com\/it\/wp-json\/wp\/v2\/pages\/939","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/expanite.com\/it\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/expanite.com\/it\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/expanite.com\/it\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/expanite.com\/it\/wp-json\/wp\/v2\/comments?post=939"}],"version-history":[{"count":19,"href":"https:\/\/expanite.com\/it\/wp-json\/wp\/v2\/pages\/939\/revisions"}],"predecessor-version":[{"id":9267,"href":"https:\/\/expanite.com\/it\/wp-json\/wp\/v2\/pages\/939\/revisions\/9267"}],"up":[{"embeddable":true,"href":"https:\/\/expanite.com\/it\/wp-json\/wp\/v2\/pages\/928"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/expanite.com\/it\/wp-json\/wp\/v2\/media\/169"}],"wp:attachment":[{"href":"https:\/\/expanite.com\/it\/wp-json\/wp\/v2\/media?parent=939"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}